Here is a list of 25 characters from DC that are Tattooed. There is maybe a handful or more not included for various reasons such as only having one obscure appearance.
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Sun-Chained-In-Ink: After tattooing Maori markings onto himself Hemi Kiwara became Sun-Chained-In-Ink and was given the power of the sun.
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Tattooed Man (Richards): Mark Richards is the third Tattooed Man. He can control the tattoos on his body which he says are the sins of the people he’s killed.
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Tattooed Man (Tarrant): The original Tattooed Man. Abel Tarrant also has control over the tattoos on his body.
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Mr. Zsasz: Zsasz marks his body every time he kills someone.
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Shado: Shado has a dragon tattoo wrapping around her arm and shoulder.
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Roulette: Roulette has a snake tattoo that wraps around her body from the shoulders onto the leg. She also has a tattoo under her right eye.
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Spider Jerusalem: Spider Jerusalem has multiple tattoos covering his body including a signature spider on top of his head.
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Dr. Manhattan: Dr. Manhattan marked himself with the symbol of the hydrogen atom.
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Rose Tattoo: Rose has tattoos covering almost her entire body.
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Grunge: Grunge has a skull with wings on his chest.
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El Diablo (Santana): The third El Diablo has tribal tattooes covering his back and arms.
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Pix: Pix has tattooes covering most of her body using “nanite ink” which allows her to create and bring to life tattoos.
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Constantine Drakon: Drakon has a large tribal dragon covering his back.
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Jack Knight: Knight has a tattoo of a winged lion partially covered by a kanji symbol on his upper left arm and a tattoo on his chest.
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John Constantine: John has tattoos related to magic covering his torso and arms.
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Starling: The Birds of Prey member has a full sleeve tattoo on her left arm that extends onto the shoulder and neck.
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Grace Choi: Choi has tattoos on her arms and stomach.
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Encantadora: Encantadora has a tattoo over her left eye and on each of her forearms.
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Simon Baz: The Green Lantern has “Courage” in Arabic tattooed on his right forearm.
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Weather Witch: The daughter of the Weather Wizard has tattoo sleeves on both arms and a yin/yang symbol on her head.
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Calender Man: Julian Day has abbreviations of each month tattooed around his head.
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Batwoman: Kate Kane has a star on her back and an arrowhead on her right arm.
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Scandal Savage: Scandal has a tattoo on her right arm.
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Doctor Mist: Dr. Mist has tattoos of magic symbols covering most of his body.
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King Snake: Bane’s father has a snake tattoo on his front torso.