I was unstoppable as Starfire (how I got a few of the trophies and a lot of hate messages) but I really liked playing Red Hood
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I play Harley Quinn, Black Canary, poison ivy, and cat woman. My favorite dc ladies and badasses. 
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Personally I’m a big Gotham/Bat family fan, so my main set consists of: Batman, Red Hood, Harley and Bane.
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Black Canary, Starfire, Harley, and Red Hood in that order.
The first two I leveled up so much, and last time I played I was working on the other two.
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Huge fan of starfire and the turtles. Alot of good move sets with them
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Main lady is without a doubt is Black Canary, I love how fast she and I can use her canary cry from far away, and with some moved sets when an opponent wants to strike she reverse them.
Then the ninja Turles, specifically leo because i was a huge Turtle fan as a kid, Like BC Leo is fast, he can call the other turtles, and they have the best level 3 in the game.
Last are Sub zero and supergirl. Can’t really think of a reason why I like them. I just do.
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When I used to play the game my mains were Green Arrow and Green Lantern. Also played a bit with Black Adam.
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I love this question. I use Black Canary the most, followed by Swamp Thing, and Ivy. I have come to really enjoy Green Arrow too. I’d like to play Wonder Woman but I"m just not fan of her in that universe.
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Personally I thought Red Hood, Star Fire and TMNT alone made the additional fighters worth it. All good things lol
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The game in general is really good. Im not in to those fighting games as much as i was as a kid, but i can always go back to that and be entertained